F. J. Cavani and J. H. Teles, Sustainability in catalytic oxidation: an alternative approach or a structural evolution, ChemSusChem, vol.2, pp.508-534, 2009.

R. A. Sheldon, I. W. Arends, and U. Hanefeld, In Green Chemistry and Catalysis, 2007.

B. Meunier, S. P. Visser, and S. Shaik, Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes, Chem. Rev, vol.104, pp.3947-3980, 2004.

I. G. Denisov, T. M. Makris, S. G. Sligar, and I. Schlichting, Structure and Chemistry of Cytochrome P450, Chem. Rev, vol.105, pp.2253-2278, 2005.

P. R. Ortiz-de-montellano, Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes, Chem. Rev, vol.110, pp.932-948, 2010.

X. Huang and J. T. Groves, Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins, Chem. Rev, vol.118, pp.2491-2553, 2018.

V. R. Kaila, M. I. Verkhovsky, and M. Wikstrom, Proton-Coupled Electron Transfer in Cytochrome Oxidase, Chem. Rev, vol.110, pp.7062-7081, 2010.

S. Yoshikawa and A. Shimada, Reaction mechanism of cytochrome c oxidase, Chem. Rev, vol.115, 1936.

J. T. Groves and Y. Han, Models and mechanisms of Cytochrome P450 Action, P. R, 1995.

F. Tani, M. Matsu-ura, S. Nakayama, and Y. Naruta, Synthetic models for the active site of cytochrome P450, Coord. Chem. Rev, vol.226, pp.219-226, 2002.

J. P. Collman, R. Boulatov, C. Sunderland, and L. Fu, Functional Analogues of Cytochrome c Oxidase, Myoglobin, and Hemoglobin, Chem. Rev, vol.104, pp.561-588, 2004.

M. L. Pegis, B. A. Mckeown, N. Kumar, K. Lang, D. J. Wasylenko et al., Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions, ACS Cent. Sci, vol.2, pp.850-856, 2016.

M. L. Pegis, D. J. Martin, C. F. Wise, A. C. Brezny, S. I. Johnson et al., Mechanism of Catalytic O 2 Reduction by Iron Tetraphenylporphyrin, J. Am. Chem. Soc, vol.141, pp.8315-8326, 2019.

E. Anxolabehere-mallart, J. Bonin, C. Fave, and M. Robert, Smallmolecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies, Dalton Trans, vol.48, pp.5869-5878, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02316700

R. Oliveira, W. Zouari, C. Herrero, F. Banse, B. Schollhorn et al., Anxolabehere-Mallart, E. Characterization and Subsequent Reactivity of an Fe-Peroxo Porphyrin Generated by Electrochemical Reductive Activation of O 2, Inorg. Chem, vol.55, 2016.

C. Gueutin, D. Lexa, J. M. Saveánt, and D. L. Wang, ?-Alkyl Iron Porphyrins from Sterically Encumbered Alkyl Halides and lron, Porphyrins. Organometallics, vol.8, pp.1607-1613, 1989.

J. Saveánt, Elements of Molecular and Biomolecular Electrochemistry, 2006.

D. J. Wasylenko, C. Rodríguez, M. L. Pegis, and J. M. Mayer, Direct comparison of electrochemical and spectrochemical kinetics for catalytic oxygen reduction, J. Am. Chem. Soc, vol.136, pp.12544-12547, 2014.

K. Izutsu, Acid-Base Dissociation Constants in Dipolar Aprotic Solvents, Blackwell Scientific Publications, vol.35, p.166, 1990.

C. Costentin, H. Dridi, and J. M. Saveánt, Molecular Catalysis of O 2 Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways, J. Am. Chem. Soc, vol.137, pp.13535-13544, 2015.

Y. H. Wang, P. E. Schneider, Z. K. Goldsmith, B. Mondal, S. Hammes-schiffer et al., Bronsted Acid Scaling Relationships Enable Control Over Product Selectivity from O 2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst, ACS Cent. Sci, vol.5, pp.1024-1034, 2019.

K. Mittra, S. Chatterjee, S. Samanta, and A. Dey,

, + O 2 reduction by an iron(tetraferrocenyl)porphyrin complex: from proton transfer followed by electron transfer in organic solvent to proton coupled electron transfer in aqueous medium, Inorg. Chem, issue.24, pp.14317-14342, 2013.

H. Kim, P. J. Rogler, S. K. Sharma, A. W. Schaefer, E. I. Solomon et al., Heme-Fe(III) Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: Fe III -O 2 ?? Complex H-Atom Abstraction Reactivity, J. Am. Chem. Soc, vol.2020, issue.6, pp.3104-3116

A. Franke, C. Fertinger, and R. Van-eldik, Axial Ligand and Spin-State Influence on the Formation and Reactivity of Hydroperoxo? Iron(III) Porphyrin Complexes, Chem. -Eur. J, vol.18, pp.6935-6949, 2012.

Z. Pan and M. Newcomb, Kinetics and Mechanism of Oxidation Reactions of Porphyrin-Iron(IV)-Oxo Intermediates, Inorg. Chem, vol.46, pp.6767-6774, 2007.

Z. Cong, S. Yanagisawa, T. Kurahashi, T. Ogura, S. Nakashima et al., Synthesis, characterization, and reactivity of hypochloritoiron(III) porphyrin complexes, J. Am. Chem. Soc, vol.134, 2012.

Z. Cong, T. Kurahashi, and H. Fujii, Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin pi-cation radicals, Angew. Chem., Int. Ed, vol.50, pp.9935-9939, 2011.

S. Yokota and H. Fujii, Critical Factors in Determining the Heterolytic versus Homolytic Bond Cleavage of Terminal Oxidants by Iron(III) Porphyrin Complexes, J. Am. Chem. Soc, vol.140, issue.15, pp.5127-5137, 2018.

K. Sengupta, S. Chatterjee, S. Samanta, and A. Dey, Direct observation of intermediates formed during steady-state electrocatalytic O 2 reduction by iron porphyrins, Proc. Natl. Acad. Sci. U. S. A, vol.110, pp.8431-8436, 2013.

K. Sengupta, S. Chatterjee, and A. Dey, Situ Mechanistic Investigation of O 2 Reduction by Iron Porphyrin Electrocatalysts Using Surface-Enhanced Resonance Raman Spectroscopy Coupled to Rotating Disk Electrode (SERRS-RDE) Setup, ACS Catal, vol.6, issue.10, pp.6838-6852, 2016.

S. Minteer and P. Baran, Electrifying Synthesis: Recent Advances in the Methods, Materials, and Techniques for Organic Electrosynthesis, Acc. Chem. Res, vol.2020, issue.3, pp.545-546

E. Anxolabehere-mallart and F. Banse, Bioinspired molecular catalysts for homogenous electrochemical activation of dioxygen. Current Opinion in Electrochemistry, vol.15, pp.118-124, 2019.

K. Sengupta, S. Chatterjee, S. Samanta, S. Bandyopadhyay, and A. Dey, Resonance Raman and electrocatalytic behavior of thiolate and imidazole bound iron porphyrin complexes on self assembled monolayers: functional modeling of cytochrome P450, Inorg. Chem, vol.52, issue.4, pp.2000-2014, 2013.

C. Gueutin and D. Lexa, Low temperature spectroelectrochemistry for the characterization of highly reduced ?-alkyl iron halogenated porphyrins, Electroanalysis, vol.8, pp.1029-1033, 1996.