 |
Journal articles
Electrocatalytic O 2 Activation by Fe Tetrakis(pentafluorophenyl)porphyrin in Acidic Organic Media. Evidence of High-Valent Fe Oxo Species
Abstract : O2 activation under mild conditions remains a weighty challenge for chemists. Herein we report a study of electrochemical O2 reductive activation catalyzed by Fe III (F20 TPP)Cl, by means of cyclic voltammetry and UV−vis spectroelectrochemistry in acidic solutions of N,N-dimethylformamide. Two parallel catalytic pathways have been evidenced occurring at different overpotentials. At high overpotential a classical electron−proton (EPT) pathway where protonation of Fe peroxo ultimately leads to the formation of high-valent Fe oxo species dominates. At low overpotential a proton−electron (PET) pathway involving a hydrosuperoxo species has been identified.
Cited literature [35 references]
https://hal-univ-paris.archives-ouvertes.fr/hal-02951618
Contributor : Claire Fave <>
Submitted on : Monday, September 28, 2020 - 5:58:50 PM
Last modification on : Wednesday, June 2, 2021 - 4:27:02 PM
Long-term archiving on: : Tuesday, December 29, 2020 - 7:12:47 PM
Contributor : Claire Fave <>
Submitted on : Monday, September 28, 2020 - 5:58:50 PM
Last modification on : Wednesday, June 2, 2021 - 4:27:02 PM
Long-term archiving on: : Tuesday, December 29, 2020 - 7:12:47 PM
File
InorgChem_2020_Nikos_HAL.pdf
Files produced by the author(s)