Electrochemical activation of halogen bonding - Université Paris Cité Accéder directement au contenu
Article Dans Une Revue Current Opinion in Electrochemistry Année : 2019

Electrochemical activation of halogen bonding

Claire Fave

Résumé

In the past, noncovalent interactions have been extensively studied by electrochemical methods. In this context, halogen bonding (XB) has been a long-time overlooked item in the toolbox of supramolecular chemistry. The article is treating electrochemical activation of XB in solution and at the solid–liquid interface. Key principles and recent work on the use of electrochemistry as a tool for detecting and controlling XB are reported. Different types of redox-switching XB are identified in the context of molecular recognition and detection. First evidence for XB promoted electron transfer reactions involving the activation of covalent bonds represents a completely new and emerging domain, ripe for exploration.
Fichier principal
Vignette du fichier
current opinion_2019_HAL.pdf (567.1 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02315119 , version 1 (14-10-2019)

Licence

Paternité

Identifiants

Citer

Claire Fave, Bernd Schöllhorn. Electrochemical activation of halogen bonding. Current Opinion in Electrochemistry, 2019, 15, pp.89-96. ⟨10.1016/j.coelec.2019.04.005⟩. ⟨hal-02315119⟩
152 Consultations
486 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More