Electrochemical activation of halogen bonding - Archive ouverte HAL Access content directly
Journal Articles Current Opinion in Electrochemistry Year : 2019

Electrochemical activation of halogen bonding

(1) , (1)
1
Claire Fave

Abstract

In the past, noncovalent interactions have been extensively studied by electrochemical methods. In this context, halogen bonding (XB) has been a long-time overlooked item in the toolbox of supramolecular chemistry. The article is treating electrochemical activation of XB in solution and at the solid–liquid interface. Key principles and recent work on the use of electrochemistry as a tool for detecting and controlling XB are reported. Different types of redox-switching XB are identified in the context of molecular recognition and detection. First evidence for XB promoted electron transfer reactions involving the activation of covalent bonds represents a completely new and emerging domain, ripe for exploration.
Fichier principal
Vignette du fichier
current opinion_2019_HAL.pdf (567.1 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

hal-02315119 , version 1 (14-10-2019)

Licence

Attribution - CC BY 4.0

Identifiers

Cite

Claire Fave, Bernd Schöllhorn. Electrochemical activation of halogen bonding. Current Opinion in Electrochemistry, 2019, 15, pp.89-96. ⟨10.1016/j.coelec.2019.04.005⟩. ⟨hal-02315119⟩
138 View
398 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More