Single LiBH4 nanocrystal stochastic impacts at a micro water|ionic liquid interface

Jane Talia Stockmann (1) , Jean-François Lemineur (1) , Huiyin Liu (1) , Claudio Cometto (2) , Marc Robert (2) , Catherine Combellas (3) , Frédéric Kanoufi (1)

1 ITODYS (UMR_7086) - Interfaces, Traitements, Organisation et Dynamique des Systèmes
2 LEM (UMR_7591) - Laboratoire d'Electrochimie Moléculaire
3 PECSA - Physicochimie des Electrolytes, Colloïdes et Sciences Analytiques

LiBH4 is often employed as a reducing agent for metal nanoparticle (NP) preparation but is inherently a solid-state H2 hydrogen storage agent. Herein it is shown, through a combination of electron/optical microscopies and single entity electrochemical study, that LiBH4 is stored in the solid state within an ionic liquid (IL) as nanocrystals (NCs). The electrochemical monitoring of an immiscible water|IL (w|IL) micro-liquid|liquid interface (LLI) shows interfa-cial charge exchange associated with the stochastic impacts of single NCs. Meanwhile, in situ optical monitoring of a w|metal or w|IL interface shows that such impacts are associated with the development of a H2-in-IL micro/nano-foam related to the poor solubility of H2. Both the presence of solid NCs and the latter H2-in-IL foam suggest that H2 release from LiBH4-in-IL is a slow, but likely controlled process. The rate of H2 production at a macroscopic LLI is further confirmed by gas chromatographic measurements, in very good agreement with microscopic observations. The electrochemical LLI provides unique investigative access to LiBH4 NCs and offers insight into H2 storage in ILs, or for direct borohydride fuel cells, as well as NP synthesis.

Domaines: Chimie analytique; Chimie théorique et/ou physique

Jane Talia Stockmann, Jean-François Lemineur, Huiyin Liu, Claudio Cometto, Marc Robert, et al.. Single LiBH4 nanocrystal stochastic impacts at a micro water|ionic liquid interface. Electrochimica Acta, 2018. ⟨hal-01974517⟩