A. Magasinski, P. Dixon, B. Hertzberg, A. Kvit, J. Ayala et al., High-performance lithium-ion anodes using a hierarchical bottom-up approach, Nature Materials, vol.299, issue.8, pp.353-358, 2010.
DOI : 10.1016/S0021-8502(03)00029-6

G. Godeau, T. Darmanin, and F. Guittard, Switchable surfaces from highly hydrophobic to highly hydrophilic using covalent imine bonds, Journal of Applied Polymer Science, vol.12, issue.11
DOI : 10.1039/CS9831200309

URL : https://hal.archives-ouvertes.fr/hal-01224872

J. Wang, J. Li, N. Li, X. Guo, L. He et al., He, R.; Qian, Z.; Cao, Y

Y. Chen, A Bottom-Up Approach to Dual Shape-Memory Effects, Chem Mater, vol.2015, issue.277, pp.2439-2448

L. Santos, P. Martin, J. Ghilane, P. C. Lacaze, and J. Lacroix, Micro/Nano-Structured Polypyrrole Surfaces on Oxidizable Metals as Smart Electroswitchable Coatings, Multifunctional and Stable Monolayers on Carbon: A Simple and Reliable Method for Backfilling Sparse Layers Grafted from Protected Aryldiazonium Ions, pp.32-2626
DOI : 10.1021/am402846n

L. Lee, Y. R. Leroux, P. Hapiot, and A. J. Downard, Amine-Terminated Monolayers on Carbon: Preparation, Characterization, and Coupling Reactions, Langmuir, vol.31, issue.18, pp.31-5071
DOI : 10.1021/acs.langmuir.5b00730

URL : https://hal.archives-ouvertes.fr/hal-01151346

L. Xu, W. Chen, A. Mulchandani, and Y. Yan, Reversible Conversion of Conducting Polymer Films from Superhydrophobic to Superhydrophilic, Angew Chem Int Ed, issue.37, pp.44-6009, 2005.

E. Hermelin, J. Petitjean, J. Lacroix, K. I. Chane-ching, J. Tanguy et al., Ultrafast Electrosynthesis of High Hydrophobic Polypyrrole Coatings on a Zinc Electrode: Applications to the Protection against Corrosion, pp.20-4447, 2008.

X. Wang, M. Berggren, O. Inganäs, L. Xu, J. Wang et al., Dynamic Control of Surface Energy and Topography of Microstructured Conducting Polymer Films, Electrically Tunable Polypyrrole Inverse Opals with Switchable Stopband, Conductivity, and Wettability, pp.5942-5948, 2008.
DOI : 10.1021/la704006z

M. Lacroix, J. C. Martin, P. Lacroix, J. Santos, L. Ghilane et al., Formation of Mixed Organic Layers by Stepwise Electrochemical Reduction of Diazonium Compounds 1-Pyrrolyl-10- decylammoniumphosphonate monolayer: a molecular nanolink between electropolymerized pyrrole films and nickel or titanium surfaces Nanoelectronics from the bottom up, Highly Resolved Nanostructured PEDOT on Large Areas by Nanosphere Lithography and Electrodeposition. ACS Applied Materials & Interfaces 2015 McCreery, R. L., Molecular Electronic Junctions, pp.16103-16109, 2004.

G. Sedghi, V. M. García-suárez, L. J. Esdaile, H. L. Anderson, C. J. Lambert et al., Long-range electron tunnelling in oligo-porphyrin molecular wires, Nature Nanotechnology, vol.14, issue.8, pp.517-523, 2011.
DOI : 10.1088/0953-8984/14/11/302

URL : https://digital.csic.es/bitstream/10261/41334/3/accesoRestringido.pdf

J. C. Lacroix, Activationless charge transport across 4.5 to 22 nm in molecular electronic junctions, Proc Natl Acad Sci, vol.110, issue.14, pp.5326-5356

L. Yuan, R. Breuer, and L. Jiang, A Molecular Diode with a Statistically Robust Rectification Ratio of Three Orders of Magnitude, Nano Letters, vol.15, issue.8, pp.150721171048008-150721171048008
DOI : 10.1021/acs.nanolett.5b02014

, Page, vol.22, p.24

H. Choi, S. Kim, B. Frisbie, and C. D. , Electrical Resistance of Long Conjugated Molecular Wires, Science, vol.117, issue.2, pp.1482-1486, 2008.
DOI : 10.1103/PhysRevLett.97.026801

A. , Experimental Approaches for Controlling Current Flowing through Metal?Molecule?Metal Junctions, Adv Mater, vol.18, issue.10, pp.1323-1328, 2006.

N. Tuccitto, V. Ferri, M. Cavazzini, S. Quici, G. Zhavnerko et al., Highly conductive ???40-nm-long molecular wires??assembled by stepwise incorporation of??metal??centres, Nature Materials, vol.1, issue.1, pp.41-46, 2009.
DOI : 10.1039/b613347a

S. H. Choi, C. Risko, M. C. Delgado, B. Kim, J. Brédas et al., Transition from Tunneling to Hopping Transport in Long, Conjugated Oligo-imine Wires Connected to Metals, Journal of the American Chemical Society, vol.132, issue.12, pp.132-4358, 2010.
DOI : 10.1021/ja910547c

R. L. Mccreery, H. Yan, A. J. Bergren, P. Martin, M. L. Della-rocca et al., A critical perspective on molecular electronic junctions: there is plenty of room in the middle Organic Electrodes Based on Grafted Oligothiophene Units in Ultrathin, Large-Area Molecular Junctions Bilayer Molecular Electronics: All-Carbon Electronic Junctions Containing Molecular Bilayers Made with " Click " Chemistry, PCCP J Am Chem Soc J Am Chem Soc, vol.2013, issue.201335, pp.1065-1081

C. Fave, Y. Leroux, G. Trippé, H. Randriamahazaka, V. Noel et al., Tunable Electrochemical Switches Based on Ultrathin Organic Films, Journal of the American Chemical Society, vol.129, issue.7, pp.129-1890, 2007.
DOI : 10.1021/ja068143u

C. Fave, V. Noel, J. Ghilane, G. Trippé-allard, H. Randriamahazaka et al., Electrochemical Switches Based on Ultrathin Organic Films: From Diode-like Behavior to Charge Transfer Transparency, The Journal of Physical Chemistry C, vol.112, issue.47, pp.112-18638, 2008.
DOI : 10.1021/jp806827a

V. Stockhausen, G. Trippé-allard, N. Van-quynh, J. Ghilane, J. Lacroix et al., Grafting ??-Conjugated Oligomers Incorporating 3,4-Ethylenedioxythiophene (EDOT) and Thiophene Units on Surfaces by Diazonium Electroreduction, The Journal of Physical Chemistry C, vol.119, issue.33, 19218.
DOI : 10.1021/acs.jpcc.5b05456

J. Lacroix, G. Allard, and J. Lacroix, Grafting Oligothiophenes on Surfaces by Diazonium Electroreduction: A Step toward Ultrathin Junction with Well-Defined Metal/Oligomer Interface Synthesis of nitro-and amino-functionalized ?conjugated oligomers incorporating 3,4-ethylenedioxythiophene (EDOT) units, J Am Chem Soc Tetrahedron, vol.131, issue.20132, pp.14920-14927, 2009.

M. P. Doyle and W. J. Bryker, Alkyl nitrite-metal halide deamination reactions. 6. Direct synthesis of arenediazonium tetrafluoroborate salts from aromatic amines, tert-butyl nitrite, and boron trifluoride etherate in anhydrous media, The Journal of Organic Chemistry, vol.44, issue.9, pp.1572-1574, 1979.
DOI : 10.1021/jo01323a048

S. Baranton and D. Bélanger, In situ generation of diazonium cations in organic electrolyte for electrochemical modification of electrode surface, Electrochimica Acta, vol.53, issue.23, pp.53-6961, 2008.
DOI : 10.1016/j.electacta.2008.02.105

T. Fluteau, C. Bessis, C. Barraud, M. L. Della-rocca, and P. Martin,

P. Lafarge, Tuning the thickness of electrochemically grafted layers in large area molecular junctions, J Appl Phys, vol.2014, issue.11611, pp.114509-114546
URL : https://hal.archives-ouvertes.fr/hal-01822392

C. Amatore, J. M. Savéant, and D. Tessier, Charge transfer at partially blocked surfaces, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.147, issue.1-2
DOI : 10.1016/S0022-0728(83)80055-2

, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.147, issue.38, pp.39-51, 1983.

J. C. Lacroix and A. F. Diaz, Electrolyte Effects on the Switching Reaction of Polyaniline

, J Electrochem Soc, vol.135, issue.6, pp.1457-1463, 1988.

D. Nguyen, T. Camalet, J. L. Lacroix, J. C. Aeiyach, S. Pham et al., Polyaniline electrodeposition from neutral aqueous media: Application to the deposition on oxidizable metals, Synthetic Metals, vol.102, issue.1-3, pp.1388-1389, 1999.
DOI : 10.1016/S0379-6779(98)01019-4

J. C. Lacroix, K. I. Chane-ching, F. Maquère, and F. Maurel, Intrachain Electron Transfer in Conducting Oligomers and Polymers:?? The Mixed Valence Approach, Journal of the American Chemical Society, vol.128, issue.22, pp.128-7264, 2006.
DOI : 10.1021/ja060390a

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